Crystal structure of (NH4)2Mg(ZrF6)2 ∙ 2H2O and peculiarities of structure formation in genetically related crystal hydrates of compositions MgZrF6 · 2H2O, Li2Mg(ZrF6)2 · 4H2O, Cs1,73(H2O)0,27MgZr2F11,73 · 2H2O and (NH4)2Mg(ZrF6)2 ∙ 2H2O

Authors

  • Ксения Анатольевна Гайворонская Институт химии ДВО РАН
  • Нина Алексеевна Диденко Институт химии ДВО РАН
  • Андрей Владимирович Герасименко Институт химии ДВО РАН

Keywords:

fluoridozirconate, crystal structure, crystalline hydrate, thermal analysis

Abstract

The structure and thermal stability of a new synthesized fluoridozirconate of the composition (NH4)2Mg(ZrF6)2 ×2H2O was investigated. Peculiarities of the crystal hydrates structure of compositions MgZrF6 · 2H2O, i2Mg(ZrF6)2 ×4H2O, Cs1,73(H2O)0,27MgZr2F11,73 · 2H2O and (NH4)2Mg(ZrF6)2 ∙ 2H2O as genetically related compounds were discussed.
The comparative evaluation of its thermal stability was provided.

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Published

2019-02-14

How to Cite

Гайворонская, К. А., Диденко, Н. А., & Герасименко, А. В. (2019). Crystal structure of (NH4)2Mg(ZrF6)2 ∙ 2H2O and peculiarities of structure formation in genetically related crystal hydrates of compositions MgZrF6 · 2H2O, Li2Mg(ZrF6)2 · 4H2O, Cs1,73(H2O)0,27MgZr2F11,73 · 2H2O and (NH4)2Mg(ZrF6)2 ∙ 2H2O. Vestnik of the Far East Branch of the Russian Academy of Sciences, (5), 18–24. Retrieved from http://vestnikdvo.ru/index.php/vestnikdvo/article/view/46

Issue

No. 5 (2018)

Section

Статьи