Anticorrosive coatings on magnesium MA8 alloy containing carbonate-substituted hydroxyapatite

Authors

  • Marina V. Sidorova Institute of Chemistry, FEB RAS, Vladivostok, Russia
  • Anatoly B. Podgorbunskiy Institute of Chemistry, FEB RAS, Vladivostok, Russia
  • Aleksandra G. Zavidnaya Institute of Chemistry, FEB RAS, Vladivostok, Russia
  • Valeriia S. Filonina Institute of Chemistry, FEB RAS, Vladivostok, Russia
  • Grigoriy A. Zverev Institute of Chemistry, FEB RAS, Vladivostok, Russia
  • Andrey S. Gnedenkov Institute of Chemistry, FEB RAS, Vladivostok, Russia
  • Sergey L. Sinebryukhov Institute of Chemistry, FEB RAS, Vladivostok, Russia
  • Sergey V. Gnedenkov Institute of Chemistry, FEB RAS, Vladivostok, Russia

Keywords:

magnesium, hydroxyapatite, plasma electrolytic oxidation, bioresorbable implants, electrochemical impedance spectroscopy

Abstract

The results of the optimization of the method for formation of bioactive calcium-phosphate coatings on bioresorbable magnesium substrate are presented. The coatings obtained by plasma electrolytic oxidation are positioned as bioresorbable and are used as anticorrosive, providing the controlled dissolution of a metal (magnesium) implant in the human body environment. A magnesium alloy of the Mg–Mn–Ce system was used as a substrate for the formed protective layers. The morphology, phase and elemental composition of the protective layers formed on the metal surface have been studied. The comparative analysis of the physicochemical properties of coated samples indicates the possibility of varying the protective characteristics and corrosion damage of the substrate material due to the use of carbonate-substituted hydroxyapatite, which is characterized by increased solubility.

Author Biographies

Marina V. Sidorova, Institute of Chemistry, FEB RAS, Vladivostok, Russia

Candidate of Sciences in Chemistry, Researcher 

http://orcid.org/0000-0003-3606-4682

Anatoly B. Podgorbunskiy, Institute of Chemistry, FEB RAS, Vladivostok, Russia

Candidate of Sciences in Chemistry, Senior Researcher

http://orcid.org/ 0000-0002-0764-391X

Aleksandra G. Zavidnaya, Institute of Chemistry, FEB RAS, Vladivostok, Russia

Candidate of Sciences in Chemistry, Researcher

 

Valeriia S. Filonina, Institute of Chemistry, FEB RAS, Vladivostok, Russia

Junior Researcher

http://orcid.org/0000-0002-9544-3597

Grigoriy A. Zverev, Institute of Chemistry, FEB RAS, Vladivostok, Russia

Candidate of Sciences in Chemistry, Researcher

Andrey S. Gnedenkov, Institute of Chemistry, FEB RAS, Vladivostok, Russia

Professor of RAS, Doctor of Sciences in Chemistry, Leading Researcher 

http://orcid.org/0000-0002-9822-7849

Sergey L. Sinebryukhov, Institute of Chemistry, FEB RAS, Vladivostok, Russia

Corresponding Member of RAS, Doctor of Sciences in Chemistry, Deputy Director 

http://orcid.org/0000-0002-0963-0557

Sergey V. Gnedenkov, Institute of Chemistry, FEB RAS, Vladivostok, Russia

Corresponding Member of RAS, Doctor of Sciences in Chemistry, Director 

http://orcid.org/0000-0003-1576-8680

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Published

2023-12-21

How to Cite

Sidorova М. В., Podgorbunskiy А. Б., Zavidnaya А. Г., Filonina В. С., Zverev Г. А., Gnedenkov А. С., Sinebryukhov С. Л., & Gnedenkov С. В. (2023). Anticorrosive coatings on magnesium MA8 alloy containing carbonate-substituted hydroxyapatite. Vestnik of the Far East Branch of the Russian Academy of Sciences, (6), 76–91. Retrieved from http://vestnikdvo.ru/index.php/vestnikdvo/article/view/1145

Issue

No. 6 (2023)

Section

Physicochemistry of surface and nanosized systems